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Beilstein J. Org. Chem. 2013, 9, 1936–1942, doi:10.3762/bjoc.9.229
Graphical Abstract
Figure 1: Structure of furanomycin and its carba- and aza-anolgue.
Scheme 1: Gold-catalyzed cycloisomerization of α-functionalized allenes.
Scheme 2: Synthesis of propargylic electrophiles 5.
Scheme 3: Synthesis of α-hydroxyallenes 7 and α-aminoallenes 8.
Scheme 4: Synthesis of azafuranomycin analog 13a.
Scheme 5: Synthesis of (αS,2R)-(2,5-dihydro-1H-pyrrol-2-yl)glycine (22).